Probing electron correlation and nuclear dynamics in Momentum Space

نویسندگان

  • H Reza Shojaei
  • Filippo Morini
  • M. S. Deleuze
  • B. Hajgató
  • F. Morini
  • S. Knippenberg
چکیده

Orbital imaging experiments employing Electron Momentum Spectroscopy are subject to many complications, such as distorted wave effects, conformational mobility in the electronic ground state, ultra-fast nuclear dynamics in the final state, or a dispersion of the ionization intensity over electronically excited (shake-up) configurations of the cation. The purpose of the present contribution is to illustrate how a proper treatment of these complications enables us to probe in momentum space the consequences of electron correlation and nuclear dynamics in neutral and cationic states.

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تاریخ انتشار 2009